Charge renormalization
The physical electron charge can be defined in the following way:
Let us
consider two classical
charged particles
being at the rest at a large distance from each other
:
The interaction of the charges is described by the Coulomb low
,
where
is the physical charge.
From
the other side, the calculation within QED shows that, to the two lowest orders
in
, the interaction is described by the
diagrams

Their calculation yields
,
where
is the regularization parameter for the
one-photon-loop diagram. Comparing both formulas, we obtain
.
It yields
,
where
.
Therefore, in our equations we should put
that is known as the charge renormalization.
In particular, the charge renormalization makes the vacuum polarization (VP) contribution to the energy shift of an atomic level to be finite:
Interaction with
the
Coulomb field
of the nucleus
![]() |
For low-Z H-like atoms, the VP energy shift is

For the 2s state in hydrogen:
.
References
[1] J.J. Sakurai, Advanced Quantum Mechanics, 1967.
[2] V.G. Serbo and I.B. Khriplovich, Lectures on Quantum Mechanics, (Novosibirsk State University, 1999).
[3] J.D. Bjorken and S.D. Drell, Relativistic Quantum Mechanics, 1964.
[4] V.B. Berestetskii, E.M. Lifshitz, and L.P. Pitaevskii,
Relativistic Quantum Theory, 1971.
[5] W. Greiner, Quantum Mechanics. Special Chapters,
1998.
[6] W. Greiner and J. Reinhardt, Quantum Electrodynamics, 1992.
Appendix I
We
consider a
space of functions

with the boundary conditions
In this space, the momentum operator

is Hermitian and has eigenfunctions

where
. The corresponding eigenvalues are
. For any
from
the space under consideration we have

If
is real, we obtain

This expansion corresponds to the Fourier expansion in terms of the “cos” and “sin” functions:

where


For
an even function,
and, for an odd function,
. ![]()
The
boundary condition
does not mean that
is an even function.
Appendix II
Let us summarize the mass renormalization procedure
in the non-relativistic case. We start with the Schroedinger equation:

where
is the momentum operator and
is the bare electron mass. Calculating the
energy shift of the level “a” due to interaction with the quantized electromagnetic
field, we get

where
. From the other side, the interaction
with the quantized electromagnetic field shifts the electron mass by

where
is the observable electron mass. Because
we know from experiment only
, we must express all
physical quantities in terms of
but not
. With this in mind we should put in the
Schroedinger equation
and
consider the second term (which is
) by perturbation
theory.
The observable energy shift is

.
Where
in
we also can use
instead of
,
because this replacement does not affect the energy shift
in
order
.
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